Refrigerants physical properties engineering toolbox. Originally the title given was new and alternative refrigerants but i was also asked to. Refrigerants capture heat and then release it to another space by using the thermodynamic phenomena of phase changes, in which a fluid changes to a gas or vice versa in the refrigeration cycle. Refrigerants are divided into groups according to their chemical composition. Download refrigerant r4a book pdf free download link or read online here in pdf. The process is not easy, and although there are alternatives to old refrigerants, the new ones are usually not.
Didion national bureau of standards gaithersburg, md 20899 usa the advent of the international agreement limiting production of certain refrigerants because of their detrimental effects on the atrnosph,ere has caused a. Zero ozone depletion potential replacement for r22. This project was made possible with american recovery and reinvestment act of 2009 funds. This publication is designed to provide accurate and authoritative information. Download limit exceeded you have exceeded your daily download allowance. Ods include chlorofluorocarbons cfcs, hydrochlorofluorocarbons hcfcs, halons, methyl bromide, carbon tetrachloride, hydrobromofluorocarbons, chlorobromomethane, and methyl chloroform. Global warming potential of r22 is 1760 whereas gwp of all the studied refrigerant mixtures were below three and. Sydney games stated that cfc, hcfc and hfcfree refrigerants should be used 5. Ozone depletion potential of different refrigerants. Refrigerants and their environmental impact substitution of hydro chlorofluorocarbon hcfc and hfc. It has long been used in a variety of airconditioning and refrigeration applications in a variety of. Refrigerant slider calculate pressure to temperature danfoss.
Describe the numbering system used for designating refrigerants section. Epa certification core heating ventilation and air. Figure 1 depicts the progression of refrigerants from their advent through four generations. Calm, the next generation of refrigerants, bulletin of the iir, international institute of refrigeration iir, paris, france, 20081. The search for alternative refrigerants a molecular.
Ozonedepleting substances ozone layer protection us epa. Refrigerants properties pdf product data summary and thermodynamic tables. Pdf refrigerant types, issues, trends and future options. Consulting firm gluckman and jacobs announced the release of comprehensive guidance for new eu fgas regulations. R251 to r253 r261 to r262 r271 discharge to atmosphere. Natural refrigerants sustainable ozone and climatefriendly alternatives to hcfcs proklima international. Refrigerants and their environmental impact substitution.
Examples of ozone depletion and global warming potentials of refrigerants 100 yr values 11. Refrigerants containing chlorine or bromine contribute to the breakdown of the ozone layer see figure 5. R427a like other gases such as r407c is a zeotrope. The ozone depletion potential odp of a refrigerant is the relative amount of depletion to the ozone layer it can cause. Ecofriendly refrigerants as substitutes for hfc4a a. Compared to halogenated refrigerants, hydrocarbons like isobutane r600a and propane r290 offer several advantages. The process is not easy, and although there are alternatives to old refrigerants. A refrigerant global warming potential gwp is based on a ratio of the refrigerants. In the occasion of release in to the atmosphere delete as appropriate. They have been controlled by the montreal protocol since 1987 because of their ozone depleting potential and high global warming potentials. Refrigerants color codes refrigerants and their color codes.
Introduction under the montreal protocol on substances that deplete the ozone layer, article 7 of the protocol requires all parties, both developing countries also called article 5 countries and developed countries. Free flashcards to help memorize facts about practice test. May 14, 2015 ozone depletion potential of different refrigerants slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. Refrigerants having nonzero odp have either already been phasedout e. This site is like a library, you could find million book here by using search box in the header. Terms in this set 27 ozone blank is a numeric value assigned to refrigerants to compair how harmful they can be to the ozone. Refrigerants can thus also be ranked according to their impact on the stratospheric ozone layer the ozone depletion potential, odp or as greenhouse gases the global warming potential, gwp. Currently the major refrigerant is switching to hydrofluorocarbons hfcs which has zero ozone depletion potential zeroodp. Systems with natural refrigerants need around 30% less energy.
Distinguish between the refrigerants that have been in used in vapor compression systems up to now 2. Removal of chloride and fluoride containing gases is aimed with montreal protocol due to ozone depletion potential odp. American society of heating, refrigerating and air. They have a very low or zero global warming potential and zero ozone depletion potential. The american society of heating, refrigerating, and airconditioning engineers ashrae is an international leader in the field of refrigeration and air conditioning. A numerical value assigned to refrigerants to compare the destructive potential each refrigerant poses to the ozone layer compared to r11, which has an odp of 1. Refrigerant slider turns your smartphone into a convenient pressure to temperature refrigerant slider. While there is no perfect refrigerant, the chart shows that.
Chlorine free refrigerants are considered long term substitutes for ozone depleting refrigerants. Nonozone depleting substances ods do not deplete the earths protective ozone layer. No ozone depletion r410a refrigerant hfc refrigerants widely. Energy procedia 18 2012 807 a 816 18766102 a 2012 published by elsevier ltd.
Volkmar hasse, gtz proklima, germany preface volkmar hasse, gtz proklima i. Semiempirical ozone depletion potential, net global warming potential over a 100year time. Examples of ozone depletion and global warming potentials of refrigerants 100yr values 11. Heat exchangers for alternative refrigerants c ommercial refrigeration has been in the environmental spotlight for more than a decade, especially as leakage studies have revealed the true effects of hydrofluorocarbon hfc emissions. The need to find a long term solution calls for the use of natural refrigerants. Alternatives to ozone depleting refrigerants in test equipment.
Global warming potential gwp is a relative measure of how much heat a refrigerant traps in the atmosphere. However, the use of r152a and r32 is limited because of flammability. Currently the major refrigerant is switching to hydrofluorocarbons hfcs which has zero ozonedepletion potential zeroodp. Companies like honeywell are to looking into redesigning appliances like air conditioners and refrigerant applications that have a lower gwp. Other activities to help include hangman, crossword, word scramble, games, matching, quizes, and tests.
A wide range of measurements was performed on the performance of the refrigerants r4a, r290 propane, r404a, r407c, r410a, and r22 in a vapor compression experimental setup. The refrigerator and air conditioning industries have started to address the future challenges. Refrigerant selection to reduce climate impact edge buildings. Refrigerants are regulated as hazardous materials by the us epa and carb, due to their ozone depleting ability and powerful greenhouse gas potential. In this chapter is addressed the thematic of refrigerants. The ozone depletion potential odp reflects the combination of. Characteristics of some new generation refrigerants with low gwp. Way back in the stone age, people knew that food could be kept for longer in the cold, and stored meat and fruit in cool caves protected from heat and the sun. Natural refrigerants was developed as a joint effort between the national renewable energy laboratory nrel and cta architects engineers. A refrigerant is a substance or mixture, usually a fluid, used in a heat pump and refrigeration. Odp is ozone depletion potential of with re ference to cfc r11 as 1. Describe the basic chemical compositions of refrigerants and the numbering system used to classify refrigerants 3. The tool, available online, targets organizations affected by the european unions regulations aimed at phasing down the use of high global warming potential refrigerants including hfcs, pfcs and sf6.
In order from the highest to the lowest potential of ozone depletion are. Figure 2 compares the odp, gwp and energy efficiency of todays commercial refrigerants and potential future refrigerants. Explain the concepts of ozone depletion and global warming and the contribution of cfchcfchfc refrigerants to both issues 4. The regulation for the management of high global warming potential refrigerants for stationary sources carb.
The two refrigerant families most often used in air conditioning systems are hydrochlorofluorocarbons hcfcs and cfcs. Global warming potential measurement of global warming done in relation with co2,where co2 has gwp 1 lower the value of gwp better the refrigerant few examples are given below. Products that normally contain ozone depleting substances should be replaced with functionally similar products that contain nonozone depleting substances. Theres a future for natural refrigerants by monika witt chairwoman of eurammon the question as to how to prevent food from going off is probably as old as humanity itself.
While there is no perfect refrigerant, the chart shows that hcfc123 r123, hfc152a r152a and hfc32 r32 strike a good balance between odp, gwp and efficiency. Following the discovery that some of these chemical compounds may be harmful to the environment, they are being replaced with more environmentally friendly alternatives see figure 5. Through its mission to advance the arts and sciences of heating, ventilating, air conditioning and refrigerating to serve humanity and promote a sustainable world. All books are in clear copy here, and all files are secure so dont worry about it. Natural refrigerant news the official news source for. Refrigerants and their environmental impact substitution of hydro chlorofluorocarbon hcfc and hfc hydro fluorocarbon. Furthermore, natural refrigerants stand out not only by being environmentfriendly the global warming potential of ammonia is zero and that of carbon dioxide and hydrocarbons is negligibly small but above all by being energy efficient. Considerable reductions in emissions are possible, but implementing them is having a major impact. They also have good energy efficiency, but are flammable and can form an explosive mixture with air if a leak occurs. Chapter 6 introduction to refrigerants flashcards quizlet.
Unlike alkyl halide refrigerants that contain bromine or chlorine, r410a which contains only fluorine does not contribute to ozone depletion and is therefore becoming more widely used, as ozone depleting refrigerants like r22 are phased out. I will be going over the top three classes at this point in time. Refrigerants pdf classify refrigerants into primary and secondary, and discuss the important. I will be going over the top three classes at this point in. The rise in the amount of chlorine in the stratosphere matches the rise in the amount of fluorine which has different natural sources, the rise in the amount of chlorine in the stratosphere matches the rise in cfc emissions, air samples taken from the stratosphere over erupting volcanoes show that they contribute a small quantity of chlorine. This page provides information on compounds recognized as ozone depleting substances ods odsa compound that contributes to stratospheric ozone depletion. Sep 17, 2014 global warming potential measurement of global warming done in relation with co2,where co2 has gwp 1 lower the value of gwp better the refrigerant few examples are given below. According to the montreal protocol, the odp of refrigerants should be zero, i. Calculating ozone depleting potentials odp introduction the number of single component refrigerants with different thermodynamic properties suitable for different types of equipment is limited. Linde strongly advocates the use of refrigerant gases with zero ozone depletion potential and fully supports the phase out of hcfcs. Indicators for quantitative comparison of the various substancesareodp8ozonedepletionpotentialandgwp9 global warming potential, which are closely related to their atmospheric lifetime alt 10. Since then, the evolution of the utilized refrigerants was stimul. The search for refrigerants with low global warming potential gwp to replace more harmful hfcs is continuing. Ozone depletion potential of different refrigerants slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising.
Reasons that daikin addresses the environmental impact of refrigerants. Even though hfcs have a zeroodp, in some cases it has a global warming potential highgwp. Hydroflourocarbons hfcs can be short and midterm replacements, but may not be permanent due to their high global warming potential gwp 5. Download pdf daikins policy and comprehensive actions on the environmental impact of refrigerants daikins policy on the environmental impact of the refrigerant. Ozone depleting substances record book anco maritime. Policylegislation on fgases and alternatives two environmental frameworks one goal the montreal protocol and the kyoto protocol. Refrigerants and their environmental impact substitution of. Andrew, listing of refrigerants pdf, andys hvacr web page, archived from the. If you continue browsing the site, you agree to the use of cookies on this website. R11 high chlorine content gwp is 4000 r22 low chlorine content gwp is 1700 r4a no chlorine content gwp is 0. Characteristics of some new generation refrigerants with. Growing demand for refrigeration and airconditioning with diversified applications has led to a continued search. Ozone depletion potential odp of a chemical compound is the relative amount of degradation it can cause to the ozone layer.
Global warming potential gwp is a measure of how much a given mass of a gas contributes to global. Add r427a, with an initial charge of 95% of the original weight. In most cases no timeconsuming circuit rinsing is required. Semi empirical ozone depletion potential, net global warming potential over a 100 year time. Chemical refrigerants are assigned an r number which is determined systematically according. Before i can answer that question there is the need to point out that there are a variety of different classes of refrigerants that are on the market today throughout the world. Pdf the use of natural refrigerants in refrigeration and. In particular, property managers must oversee the proper management of refrigerants and refrigerantcontaining. Current and future trends of refrigerants development. The first refrigerant being marketed on a large scale was ethyl ether r610, in 1834. Nearly all of these early refrigerants were flammable, toxic, or both, and some were also highly reactive. The most common refrigerants for the first 100 years were familiar solvents and other volatile fluids.
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